Simple and Fast Microwave-Assisted Synthesis Methods of Nanocrystalline TiO 2 and rGO Materials for Low-Cost Metal-Free DSSC Applications.

Autor: Fathy M; Electronic Materials Research Department, Advanced Technology and New Materials Research Institute, City of Scientific Research and Technological Applications (SRTA-City), P.O. Box 21934, New Borg El-Arab City, Alexandria 21934, Egypt., Hassan H; Electronic Materials Research Department, Advanced Technology and New Materials Research Institute, City of Scientific Research and Technological Applications (SRTA-City), P.O. Box 21934, New Borg El-Arab City, Alexandria 21934, Egypt., Hafez H; Nanotechnology Dept. Environmental Studies and Research Institute (ESRI), University of Sadat City, Minofiya 32897, Egypt., Soliman M; Institute of Graduate Studies and Research, Alexandria University, 163 Horrya Avenue, P.O. Box 832, Shatby, Alexandria 21526, Egypt., Abulfotuh F; Institute of Graduate Studies and Research, Alexandria University, 163 Horrya Avenue, P.O. Box 832, Shatby, Alexandria 21526, Egypt., Kashyout AEHB; Electronic Materials Research Department, Advanced Technology and New Materials Research Institute, City of Scientific Research and Technological Applications (SRTA-City), P.O. Box 21934, New Borg El-Arab City, Alexandria 21934, Egypt.
Jazyk: angličtina
Zdroj: ACS omega [ACS Omega] 2022 May 06; Vol. 7 (19), pp. 16757-16765. Date of Electronic Publication: 2022 May 06 (Print Publication: 2022).
DOI: 10.1021/acsomega.2c01455
Abstrakt: Nanocrystalline TiO 2 and reduced graphene oxide (rGO) materials have been synthesized by a simple and low-cost microwave-assisted hydrothermal method and applied in dye-sensitized solar cells (DSSCs) as photoactive and metal-free counter electrodes, respectively. Different TiO 2 nanocrystalline materials have been synthesized via the acid hydrolysis sol-gel method, followed by microwave hydrothermal treatment at 210 °C and 300 psi and at different microwave irradiation times (20, 30, 45, and 60 min) instead of the usual hydrothermal time of 12 h. The properties of the produced mesoporous nanocrystalline TiO 2 are investigated in terms of their morphology, crystal structure, optical properties, and surface area behavior using relevant characterization techniques. Maximum specific surface area values ( S BET ) of 97.77 and 100.7 m 2 g -1 are measured for TiO 2 , with the average crystallite sizes of 18.6 and 17.5 nm, at microwave irradiation times of 30 and 45 min, respectively. Different rGO samples have been prepared by the modified Hummers method, followed by microwave-assisted reduction at a temperature of 200 °C and pressure of 300 psi at different microwave irradiation times (3, 17, and 25 min). The physicochemical properties of the different rGO samples in terms of morphology, crystallization, and optical properties are characterized by TEM, XRD, and Raman spectroscopic analysis. The current density J sc of the fabricated DSSCs based on TiO 2 as the photoelectrode and rGO as the counter electrode compared with DSSCs based on Pt as the counter electrode is found to be 11.25 and 9.28 mA cm -2 , respectively. Although the overall power efficiency of the fabricated DSSCs based on rGO as the counter electrode is lower than that based on the Pt electrode, the former still exhibits promising prospects for replacing Pt with low-cost metal-free carbon-based DSSCs.
Competing Interests: The authors declare no competing financial interest.
(© 2022 The Authors. Published by American Chemical Society.)
Databáze: MEDLINE
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