Polyoxometalate-based materials in extraction, and electrochemical and optical detection methods: A review.

Autor: Bagheri AR; Department of Chemistry, Yasouj University, Yasouj, 75918-74831, Iran., Aramesh N; Department of Chemistry, Isfahan University, Isfahan, 81746-73441, Iran., Chen J; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, Jiangsu Province, China., Liu W; Department of Environmental Toxicology, University of California, Davis, CA, 95616, USA., Shen W; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, Jiangsu Province, China., Tang S; School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, Jiangsu Province, China. Electronic address: tangsheng.nju@gmail.com., Lee HK; Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore. Electronic address: chmleehk@nus.edu.sg.
Jazyk: angličtina
Zdroj: Analytica chimica acta [Anal Chim Acta] 2022 May 29; Vol. 1209, pp. 339509. Date of Electronic Publication: 2022 Jan 18.
DOI: 10.1016/j.aca.2022.339509
Abstrakt: Polyoxometalates (POMs) as metal-oxide anions have exceptional properties like high negative charges, remarkable redox abilities, unique ligand properties and availability of organic grafting. Moreover, the amenability of POMs to modification with different materials makes them suitable as precursors to further obtain new composites. Due to their unique attributes, POMs and their composites have been utilized as adsorbents, electrodes and catalysts in extraction, and electrochemical and optical detection methods, respectively. A survey of the recent progress and developments of POM-based materials in these methods is therefore desirable, and should be of great interest. In this review article, POM-based materials, their properties as well as their identification methods, and analytical applications as adsorbents, electrodes and catalysts, and corresponding mechanisms of action, where relevant, are reviewed. Some current issues of the utilization of these materials and their future prospects in analytical chemistry are discussed.
(Copyright © 2022 Elsevier B.V. All rights reserved.)
Databáze: MEDLINE
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