An investigation of the role acceptor side chains play in the processibility and efficiency of organic solar cells fabricated from small molecular donors featuring 3,4-ethylenedioxythiophene cores.

Autor: Mica NA; Organic Semiconductor Centre, SUPA, School of Physics and Astronomy St Andrews Fife KY16 9SS UK., Almahmoud SAJ; Glasgow Centre for Physical Organic Chemistry (GCPOC), WestCHEM, School of Chemistry, University of Glasgow Glasgow G12 8QQ UK., Krishnan Jagadamma L; Organic Semiconductor Centre, SUPA, School of Physics and Astronomy St Andrews Fife KY16 9SS UK., Cooke G; Glasgow Centre for Physical Organic Chemistry (GCPOC), WestCHEM, School of Chemistry, University of Glasgow Glasgow G12 8QQ UK., Samuel IDW; Organic Semiconductor Centre, SUPA, School of Physics and Astronomy St Andrews Fife KY16 9SS UK.
Jazyk: angličtina
Zdroj: RSC advances [RSC Adv] 2018 Nov 23; Vol. 8 (69), pp. 39231-39240. Date of Electronic Publication: 2018 Nov 23 (Print Publication: 2018).
DOI: 10.1039/c8ra07034b
Abstrakt: Organic photovoltaic devices fabricated from small molecular donors continue to receive significant interest due to their desirable properties such as convenient synthesis, purification and batch-to-batch reproducibility. In this study, we have synthesized two small molecules based on an alternating A-D-A structure, utilizing a central EDOT donor moiety and either 2-ethylhexyl cyanoacetate (SAM-72) or N -(2-ethylhexyl)cyanoacetamide (SAM-80) units as acceptor termini. The small molecules were incorporated into bulk heterojunction solar cells with PC 71 BM. Our investigations have shown that the side chains utilized for SAM-80 only allow for solution processing using volatile solvents, such as chloroform, which limits the reproducibility of device fabrication. However, SAM-72 displays better solubility and devices fabricated using a SAM-72:PC 71 BM active layer reached average power conversion efficiencies of 1.9%, with fill factors reaching 60%. Post-processing methods such as thermal and solvent vapor annealing were found to significantly increase the stability of devices, but were not able to improve overall device performance.
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE