New zinc complexes derived from "self-adaptable" acyclic diiminodipyrromethanes as potent catalysts for the reduction of curing temperature of bisphenol-A/F benzoxazines.
Autor: | Loke SK; Division of Chemistry, Department of Sciences and Humanities, Vignan's Foundation for Science Technology and Research (Deemed to be University) Vadlamudi Guntur-522213 Andhra Pradesh India ravikottalanka@gmail.com +91 863 2344 707 +91 863 2344 700., Pagadala E; Division of Chemistry, Department of Sciences and Humanities, Vignan's Foundation for Science Technology and Research (Deemed to be University) Vadlamudi Guntur-522213 Andhra Pradesh India ravikottalanka@gmail.com +91 863 2344 707 +91 863 2344 700., Devaraju S; Division of Chemistry, Department of Sciences and Humanities, Vignan's Foundation for Science Technology and Research (Deemed to be University) Vadlamudi Guntur-522213 Andhra Pradesh India ravikottalanka@gmail.com +91 863 2344 707 +91 863 2344 700., Srinivasadesikan V; Division of Chemistry, Department of Sciences and Humanities, Vignan's Foundation for Science Technology and Research (Deemed to be University) Vadlamudi Guntur-522213 Andhra Pradesh India ravikottalanka@gmail.com +91 863 2344 707 +91 863 2344 700., Kottalanka RK; Division of Chemistry, Department of Sciences and Humanities, Vignan's Foundation for Science Technology and Research (Deemed to be University) Vadlamudi Guntur-522213 Andhra Pradesh India ravikottalanka@gmail.com +91 863 2344 707 +91 863 2344 700. |
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Jazyk: | angličtina |
Zdroj: | RSC advances [RSC Adv] 2020 Oct 01; Vol. 10 (60), pp. 36275-36286. Date of Electronic Publication: 2020 Oct 01 (Print Publication: 2020). |
DOI: | 10.1039/d0ra07837a |
Abstrakt: | The simple modification of the Schiff-base ligands often brings significant changes in the coordination properties of the metal-complexes, providing newer prospects for their unexplored applications. In this context, the present work utilized the "self-adaptable" acyclic diiminodipyrromethane Schiff's bases (2a and 2b) for the synthesis of their Zn-based complexes and explored their potential in the ring-opening polymerization of benzoxazines. The two zinc complexes of composition [Zn{(Ph)(CH Competing Interests: There are no conflicts to declare. (This journal is © The Royal Society of Chemistry.) |
Databáze: | MEDLINE |
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