Onion-derived activated carbons with enhanced surface area for improved hydrogen storage and electrochemical energy application.

Autor: Musyoka NM; Centre for Nanostructures and Advanced Materials (CeNAM), Chemicals Cluster, Council for Scientific and Industrial Research (CSIR) Meiring Naude Road Pretoria 0001 South Africa nmusyoka@csir.co.za +27-12-841-4806., Mutuma BK; Department of Physics, Institute of Applied Materials, SARCHI Chair in Carbon Technology and Materials, University of Pretoria South Africa bridgetmutuma@gmail.com Ncholu.manyala@up.ac.za., Manyala N; Department of Physics, Institute of Applied Materials, SARCHI Chair in Carbon Technology and Materials, University of Pretoria South Africa bridgetmutuma@gmail.com Ncholu.manyala@up.ac.za.
Jazyk: angličtina
Zdroj: RSC advances [RSC Adv] 2020 Jul 20; Vol. 10 (45), pp. 26928-26936. Date of Electronic Publication: 2020 Jul 20 (Print Publication: 2020).
DOI: 10.1039/d0ra04556j
Abstrakt: High surface area activated carbons (ACs) were prepared from a hydrochar derived from waste onion peels. The resulting ACs had a unique graphene-like nanosheet morphology. The presence of N (0.7%) and O content (8.1%) in the OPAC-800 °C was indicative of in situ incorporation of nitrogen groups from the onion peels. The specific surface area and pore volume of the best OPAC sample was found to be 3150 m 2 g -1 and 1.64 cm 3 g -1 , respectively. The hydrogen uptake of all the OPAC samples was established to be above 3 wt% (at 77 K and 1 bar) with the highest being 3.67 wt% (800 °C). Additionally, the OPAC-800 °C achieved a specific capacitance of 169 F g -1 at a specific current of 0.5 A g -1 and retained a capacitance of 149 F g -1 at 5 A g -1 in a three electrode system using 3 M KNO 3 . A symmetric supercapacitor based on the OPAC-800 °C//OPAC-800 °C electrode provided a capacitance of 158 F g -1 at 0.5 A g -1 . The maximum specific energy and power was found to be 14 W h kg -1 and 400 W kg -1 , respectively. Moreover, the device exhibited a high coulombic efficiency of 99.85% at 5 A g -1 after 10 000 cycles. The results suggested that the high surface area graphene-like carbon nanostructures are excellent materials for enhanced hydrogen storage and supercapacitor applications.
Competing Interests: There are no conflicts of interest to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE
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