Copper-exchanged large-port and small-port mordenite (MOR) for methane-to-methanol conversion.
| Autor: | Knorpp AJ; Institute for Chemical and Bioengineering, ETH Zurich Vladimir-Prelog-Weg 1 Zurich 8093 Switzerland Jeroen.vanbokhoven@chem.ethz., Pinar AB; Laboratory for Catalysis and Sustainable Chemistry, Paul Scherrer Institute Villigen 5232 Switzerland., Newton MA; Institute for Chemical and Bioengineering, ETH Zurich Vladimir-Prelog-Weg 1 Zurich 8093 Switzerland Jeroen.vanbokhoven@chem.ethz., Li T; Institute for Chemical and Bioengineering, ETH Zurich Vladimir-Prelog-Weg 1 Zurich 8093 Switzerland Jeroen.vanbokhoven@chem.ethz., Calbry-Muzyka A; Bioenergy and Catalysis Laboratory, Paul Scherrer Institut, PSI Villigen 5232 Switzerland., van Bokhoven JA; Institute for Chemical and Bioengineering, ETH Zurich Vladimir-Prelog-Weg 1 Zurich 8093 Switzerland Jeroen.vanbokhoven@chem.ethz.; Laboratory for Catalysis and Sustainable Chemistry, Paul Scherrer Institute Villigen 5232 Switzerland. |
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| Jazyk: | angličtina |
| Zdroj: | RSC advances [RSC Adv] 2021 Sep 20; Vol. 11 (49), pp. 31058-31061. Date of Electronic Publication: 2021 Sep 20 (Print Publication: 2021). |
| DOI: | 10.1039/d1ra04643h |
| Abstrakt: | Zeolite mordenite (MOR) is one of the most studied zeolites for the stepwise direct conversion of methane to methanol, but it also can exist in two forms: large port and small port. Here we report that the synthesis and selection of the parent mordenite is critical for optimizing productivity, and that large-port mordenite outperforms small-port mordenite for the stepwise conversion of methane to methanol. Competing Interests: There are no conflicts to declare. (This journal is © The Royal Society of Chemistry.) |
| Databáze: | MEDLINE |
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