The effect of the metal and selenium precursors on the properties of NbSe 2 and Nb 2 Se 9 nanostructures and their application in dye-sensitized solar cells.

Autor: Kolokoto T; Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand Private Bag 3, Wits, 2050 South Africa Kalenga.Mubiayi@wits.ac.za Nosipho.Moloto@wits.ac.za +27 11 717 6720 +27 11 717 6774., Mashindi V; Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand Private Bag 3, Wits, 2050 South Africa Kalenga.Mubiayi@wits.ac.za Nosipho.Moloto@wits.ac.za +27 11 717 6720 +27 11 717 6774., Kadzutu-Sithole R; Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand Private Bag 3, Wits, 2050 South Africa Kalenga.Mubiayi@wits.ac.za Nosipho.Moloto@wits.ac.za +27 11 717 6720 +27 11 717 6774., Machogo-Phao LFE; Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand Private Bag 3, Wits, 2050 South Africa Kalenga.Mubiayi@wits.ac.za Nosipho.Moloto@wits.ac.za +27 11 717 6720 +27 11 717 6774.; Analytical Services Division, Mintek 200 Malibongwe Drive, Randburg South Africa., Ndala ZB; Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand Private Bag 3, Wits, 2050 South Africa Kalenga.Mubiayi@wits.ac.za Nosipho.Moloto@wits.ac.za +27 11 717 6720 +27 11 717 6774., Shumbula NP; Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand Private Bag 3, Wits, 2050 South Africa Kalenga.Mubiayi@wits.ac.za Nosipho.Moloto@wits.ac.za +27 11 717 6720 +27 11 717 6774., Nkabinde SS; Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand Private Bag 3, Wits, 2050 South Africa Kalenga.Mubiayi@wits.ac.za Nosipho.Moloto@wits.ac.za +27 11 717 6720 +27 11 717 6774., Ngubeni GN; Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand Private Bag 3, Wits, 2050 South Africa Kalenga.Mubiayi@wits.ac.za Nosipho.Moloto@wits.ac.za +27 11 717 6720 +27 11 717 6774., Gqoba SS; Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand Private Bag 3, Wits, 2050 South Africa Kalenga.Mubiayi@wits.ac.za Nosipho.Moloto@wits.ac.za +27 11 717 6720 +27 11 717 6774., Mubiayi KP; Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand Private Bag 3, Wits, 2050 South Africa Kalenga.Mubiayi@wits.ac.za Nosipho.Moloto@wits.ac.za +27 11 717 6720 +27 11 717 6774., Moloto N; Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand Private Bag 3, Wits, 2050 South Africa Kalenga.Mubiayi@wits.ac.za Nosipho.Moloto@wits.ac.za +27 11 717 6720 +27 11 717 6774.
Jazyk: angličtina
Zdroj: RSC advances [RSC Adv] 2021 Sep 21; Vol. 11 (50), pp. 31159-31173. Date of Electronic Publication: 2021 Sep 21 (Print Publication: 2021).
DOI: 10.1039/d0ra10894d
Abstrakt: Herein, we report on the effect of the precursors on the structural, morphological, and optical properties of niobium selenide using the heat-up colloidal method. The metal precursor was varied from the conventional NbCl 5 to NbF 5 whilst Se, SeO 2 , and selenourea were used as the selenium precursors. The NbCl 5 and NbF 5 resulted in the formation of NbSe 2 and Nb 2 Se 9 respectively. While maintaining the two different metal precursors and varying the selenium precursor from Se, SeO 2 to selenourea, the properties of NbSe 2 and Nb 2 Se 9 changed slightly, however the effect of changing the selenium precursor was less pronounced than changing the metal precursors. From the XRD and XPS, the NbSe 2 nanostructures were more susceptible to oxidation than Nb 2 Se 9 as Nb 2 O 5 was observed in the XRD and the percentage of M-O in the XPS was much higher in NbSe 2 . NbSe 2 formed nanoflowers whilst Nb 2 Se 9 formed rods with 3.29 eV and 2.43 eV band-gaps, respectively. Also, the band-gaps were red-shifted as the selenium precursors were varied. The NbSe 2 nanoflowers and Nb 2 Se 9 nanorods were used as counter electrodes in dye-sensitized solar cells. Two methods were used to fabricate the counter electrodes i.e. spin coating and drop casting. The electrochemical properties of the spin coated counter electrodes were better than the drop casted ones; hence, they were employed in dye-sensitized solar cells. The spin coated NbSe 2 nanoflowers had the highest efficiency of 6.84%, attributed to the nanoflower morphology.
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE
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