Production of chlorine-containing functional group doped graphene powders using Yucel's method as anode materials for Li-ion batteries.

Autor: Gursu H; Yildiz Technical University, Faculty of Art and Sciences, Department of Chemistry 34220 Istanbul Turkey yucelsahin06@gmail.com +90 212 3834134 +90 212 3834411., Guner Y; Pamukkale University, Department of Metallurgy and Materials Engineering Denizli 20160 Turkey., Arvas MB; Yildiz Technical University, Faculty of Art and Sciences, Department of Chemistry 34220 Istanbul Turkey yucelsahin06@gmail.com +90 212 3834134 +90 212 3834411., Dermenci KB; Eskişehir Technical University, Department of Materials Science and Engineering Eskişehir 26555 Turkey., Savaci U; Eskişehir Technical University, Department of Materials Science and Engineering Eskişehir 26555 Turkey., Gencten M; Yildiz Technical University, Faculty of Chemical and Metallurgical Engineering, Department of Metallurgy and Materials Engineering 34210 Istanbul Turkey., Turan S; Eskişehir Technical University, Department of Materials Science and Engineering Eskişehir 26555 Turkey., Sahin Y; Yildiz Technical University, Faculty of Art and Sciences, Department of Chemistry 34220 Istanbul Turkey yucelsahin06@gmail.com +90 212 3834134 +90 212 3834411.
Jazyk: angličtina
Zdroj: RSC advances [RSC Adv] 2021 Dec 16; Vol. 11 (63), pp. 40059-40071. Date of Electronic Publication: 2021 Dec 16 (Print Publication: 2021).
DOI: 10.1039/d1ra07653a
Abstrakt: In this study, the one-step electrochemical preparation of chlorine doped and chlorine-oxygen containing functional group doped graphene-based powders was carried out by Yucel's method, with the resultant materials used as anode materials for lithium (Li)-ion batteries. Cl atoms and ClO x ( x = 2, 3 or 4) groups, confirmed by X-ray photoelectron spectroscopy analysis, were covalently doped into the graphene powder network to increase the defect density in the graphene framework and improve the electrochemical performance of Li-ion batteries. The microscopic properties of the Cl-doped graphene powder were investigated by scanning electron microscopy and transmission electron microscopy (TEM) analyses. TEM analysis showed that the one-layer thickness of the graphene was approximately 0.33 nm. Raman spectroscopy analysis was carried out to determine the defect density of the graphene structures. The G peak obtained in the Raman spectra is related to the formation of sp 2 hybridized carbons in the graphene-based powders. The 2D peak seen in the spectra shows that the synthesized graphene-based powders have optically transparent structures. In addition, the number of sp 2 hybridized carbon rings was calculated to be 22, 19, and 38 for the Cl-GP1, Cl-GP2, and Cl-GOP samples, respectively. As a result of the charge/discharge tests of the electrodes as anodes in Li-ion batteries, Cl-GP2 exhibits the best electrochemical performance of 493 mA h g -1 at a charge/discharge current density of 50 mA g -1 .
Competing Interests: There are no conflicts to declare.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE
Externí odkaz: