Non-close-packed arrangement of soft elastomer microspheres on solid substrates.

Autor: Sasaki Y; Graduate School of Textile Science & Technology, Shinshu University 3-15-1 Tokida Ueda Nagano 386-8567 Japan d_suzuki@shinshu-u.ac.jp., Hiroshige S; Graduate School of Textile Science & Technology, Shinshu University 3-15-1 Tokida Ueda Nagano 386-8567 Japan d_suzuki@shinshu-u.ac.jp., Takizawa M; Graduate School of Textile Science & Technology, Shinshu University 3-15-1 Tokida Ueda Nagano 386-8567 Japan d_suzuki@shinshu-u.ac.jp., Nishizawa Y; Graduate School of Textile Science & Technology, Shinshu University 3-15-1 Tokida Ueda Nagano 386-8567 Japan d_suzuki@shinshu-u.ac.jp., Uchihashi T; Department of Physics, Structural Biology Research Center, Graduate School of Science, Nagoya University Furo-cho, Chikusa-ku Nagoya Aichi 464-8602 Japan.; Exploratory Research Center on Life and Living Systems, National Institutes of Natural Sciences 5-1 Higashiyama, Myodaiji Okazaki Aichi 444-8787 Japan., Minato H; Graduate School of Textile Science & Technology, Shinshu University 3-15-1 Tokida Ueda Nagano 386-8567 Japan d_suzuki@shinshu-u.ac.jp., Suzuki D; Graduate School of Textile Science & Technology, Shinshu University 3-15-1 Tokida Ueda Nagano 386-8567 Japan d_suzuki@shinshu-u.ac.jp.; Research Initiative for Supra-Materials, Interdisciplinary Cluster for Cutting Edge Research, Shinshu University 3-15-1 Tokida Ueda Nagano 386-8567 Japan.
Jazyk: angličtina
Zdroj: RSC advances [RSC Adv] 2021 Apr 19; Vol. 11 (24), pp. 14562-14567. Date of Electronic Publication: 2021 Apr 19 (Print Publication: 2021).
DOI: 10.1039/d1ra02688g
Abstrakt: Unlike rigid microparticles, soft and deformable elastomer (rubber) microspheres were found to exhibit a non-close-packed arrangement on solid substrates after the evaporation of water from their dispersions. The microscopic observation revealed that individual microspheres are ordered in regular intervals at the air/water interface of a sessile droplet and remain fixed on the substrate without being affected by the capillary forces during evaporation due to their deformability. Moreover, using the Langmuir-Blodgett method, thin films of non-close-packed structures could be successfully generated over large areas. Our findings may potentially help to control the arranged structures of elastomer microspheres, which can be expected to improve the nano-science and technology for the precise control for e.g. surface patterning.
Competing Interests: The authors declare the absence of any potential conflicts of interest.
(This journal is © The Royal Society of Chemistry.)
Databáze: MEDLINE