Using solid-phase microextraction during ultrasound reveals higher aqueous PAHs release from contaminated sediment.

Autor: Kohan DS; Environmental Science Graduate Program, The Ohio State University, Columbus, OH 43210, United States., Lanno RP; Environmental Science Graduate Program, The Ohio State University, Columbus, OH 43210, United States; Department of Evolutionary Ecology and Organismal Biology, The Ohio State University, Columbus, OH 43210, United States., Weavers LK; Environmental Science Graduate Program, The Ohio State University, Columbus, OH 43210, United States; Department of Civil, Environmental, and Geodetic Engineering, The Ohio State University, Columbus, OH 43210, United States. Electronic address: weavers.1@osu.edu.
Jazyk: angličtina
Zdroj: Ultrasonics sonochemistry [Ultrason Sonochem] 2022 Apr; Vol. 85, pp. 105981. Date of Electronic Publication: 2022 Mar 12.
DOI: 10.1016/j.ultsonch.2022.105981
Abstrakt: Ultrasound (US) releases polycyclic aromatic hydrocarbons (PAHs) from contaminated creosote sediments and degrades PAHs in aqueous solution. However, it is unclear how much PAHs release occurs during active US compared to after US is stopped. In this study, solid-phase microextraction (SPME) was used to determine aqueous PAH concentrations desorbed from Little Scioto River creosote contaminated sediment during exposure to 20 kHz ultrasound (US) at a power of 430 W L -1 . First, SPME fiber-water partition coefficients,K SPME , were experimentally determined and shown to be comparable with previous studies. Next, PAH concentrations released into aqueous solution were determined by sequentially exposing fresh, conditioned SPME fibers in a reactor containing the contaminated sediment and DI for 10 min periods. Three consecutive 10 min periods each were measured during US and after US. Compared to mixing only, PAHs desorbed during ultrasound was significantly higher. In addition, for phenanthrene, anthracene, and fluoranthene, US showed significantly higher aqueous concentrations during US compared with after US. For these less soluble PAHs, desorption into the aqueous phase reaches and surpasses expected equilibrium aqueous concentrations. However, when US is ceased, PAHs appear to resorb onto sediment resulting in the lower concentrations measured in these PAH compounds after US that are similar to expected equilibrium aqueous concentrations. Typical analytical extraction methods for determining the effects of US require stopping treatment and may underestimate the potential US has for release of contaminants from sediment during US. Using SPME during US treatment reveals that the concentration of PAHs during US may surpass the expected equilibrium aqueous concentration of some PAHs congeners. To our knowledge, this higher concentration observed during US compared to after US has not been shown previously.
(Copyright © 2022 The Authors. Published by Elsevier B.V. All rights reserved.)
Databáze: MEDLINE
Externí odkaz: