Multiphoton Phosphorescence of Simple Ketones by Visible-light Excitation and Its Consideration for Active Sensing in Space.

Autor: de Prinse T; Institute for Photonics and Advanced Sensing (IPAS), The University of Adelaide, Adelaide, Australia. thomas.deprinse@adelaide.edu.au., Klantsataya E; Institute for Photonics and Advanced Sensing (IPAS), The University of Adelaide, Adelaide, Australia., Tsiminis G; Institute for Photonics and Advanced Sensing (IPAS), The University of Adelaide, Adelaide, Australia., Payten T; Institute for Photonics and Advanced Sensing (IPAS), The University of Adelaide, Adelaide, Australia., Moffatt J; Institute for Photonics and Advanced Sensing (IPAS), The University of Adelaide, Adelaide, Australia., Kee TW; Department of Chemistry, The University of Adelaide, Adelaide, Australia., Spooner NA; Institute for Photonics and Advanced Sensing (IPAS), The University of Adelaide, Adelaide, Australia.; Defence Science and Technology Group (DSTG), Edinburgh, Australia.
Jazyk: angličtina
Zdroj: Journal of fluorescence [J Fluoresc] 2022 May; Vol. 32 (3), pp. 1051-1057. Date of Electronic Publication: 2022 Mar 17.
DOI: 10.1007/s10895-022-02912-7
Abstrakt: Acetone and butanone were seen to emit blue light around 450 nm when excited in the green by a high intensity pulsed laser. The pathway of this anti-Stokes emission is believed to be multiphoton absorption followed by phosphorescence, with emission being observed in the samples at cryogenic temperatures below their melting point and not seen from either ketone in their cold liquid state. Given the widespread nature of these simple ketones in off-world bodies and their potential importance as an organic resource for Space Resource Utilization, signals which enable the identification and tracing of these materials are of use in applications from remote sensing and mapping to monitoring during extraction processes. While the excitation process has a low efficiency, the ability to use visible light for sensing of these targets has advantages over UV sources, such as the wider availability of high-powered lasers which could be utilized.
(© 2022. The Author(s).)
Databáze: MEDLINE
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