| Autor: |
Li B; Institute of Inorganic Chemistry, University of Duisburg-Essen, Essen 45117, Germany. stephan.schulz@uni-due.de., Geoghegan BL; Institute of Inorganic Chemistry, University of Duisburg-Essen, Essen 45117, Germany. stephan.schulz@uni-due.de.; Max Planck Institute for Chemical Energy Conversion (CEC), Stiftstraße 34-36, Mülheim an der Ruhr 45470, Germany. george.cutsail@cec.mpg.de., Weinert HM; Institute of Inorganic Chemistry, University of Duisburg-Essen, Essen 45117, Germany. stephan.schulz@uni-due.de., Wölper C; Institute of Inorganic Chemistry, University of Duisburg-Essen, Essen 45117, Germany. stephan.schulz@uni-due.de., Cutsail GE 3rd; Institute of Inorganic Chemistry, University of Duisburg-Essen, Essen 45117, Germany. stephan.schulz@uni-due.de.; Max Planck Institute for Chemical Energy Conversion (CEC), Stiftstraße 34-36, Mülheim an der Ruhr 45470, Germany. george.cutsail@cec.mpg.de., Schulz S; Institute of Inorganic Chemistry, University of Duisburg-Essen, Essen 45117, Germany. stephan.schulz@uni-due.de.; Center for Nanointegration Duisburg-Essen (Cenide), University of Duisburg-Essen, Duisburg 47057, Germany. |
| Abstrakt: |
Carbenes are known to stabilize main group element compounds with unusual electronic properties. Herein, we report the synthesis of carbene-stabilized group 13 metal radicals (cAAC)MX 2 (IPr) (M = Al, X = Br 3; M = Ga, X = Cl 4) and the corresponding cations [(cAAC)MX 2 (IPr)][B(C 6 F 5 ) 4 ] (M = Al, X = Br 5; M = Ga, X = Cl 6), which were characterized spectroscopically and by sc-XRD. Quantum chemical calculation gave insights into their electronic structures. |
