Metal-Thiolate Framework for Electrochemical and Photoelectrochemical Hydrogen Generation.
Autor: | Chatterjee S; School of Materials Sciences Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mallick Road, Jadavpur, Kolkata, 700032, India., Shaymal S; School of Materials Sciences Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mallick Road, Jadavpur, Kolkata, 700032, India., Mukherjee M; School of Chemical Sciences Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mallick Road, Jadavpur, Kolkata, 700032, India., Halder D; School of Chemical Sciences Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mallick Road, Jadavpur, Kolkata, 700032, India., Chongdar S; School of Materials Sciences Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mallick Road, Jadavpur, Kolkata, 700032, India., Paul A; School of Chemical Sciences Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mallick Road, Jadavpur, Kolkata, 700032, India., Bhaumik A; School of Materials Sciences Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mallick Road, Jadavpur, Kolkata, 700032, India. |
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Jazyk: | angličtina |
Zdroj: | ChemSusChem [ChemSusChem] 2022 May 20; Vol. 15 (10), pp. e202200114. Date of Electronic Publication: 2022 Mar 30. |
DOI: | 10.1002/cssc.202200114 |
Abstrakt: | Hydrogen has evolved as the cleanest and most sustainable fuel, produced directly from naturally abundant water resources. Generation of hydrogen by electrochemical or photoelectrochemical splitting of water has been conceived as the most effective method for hydrogen production. Herein, a robust solid metal-thiolate framework (MTF-1) was obtained by hydrothermal crystallization of the reaction mixture consisting of 1,3,5-triazine-2,4,6-trithioltrisodium salt and Cu II under mild synthesis conditions. The material was thoroughly characterized and explored as efficient catalyst for electrochemical and photoelectrochemical hydrogen evolution reaction (HER) via water splitting reactions. MTF-1 showed onset potential 0.045 V (© 2022 Wiley-VCH GmbH.) |
Databáze: | MEDLINE |
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