| Autor: |
Zasada LB, Guio L, Kamin AA, Dhakal D, Monahan M, Seidler GT, Luscombe CK; Okinawa Institute of Science and Technology Graduate University, Onna-son, Okinawa 904-0495, Japan., Xiao DJ |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of the American Chemical Society [J Am Chem Soc] 2022 Mar 16; Vol. 144 (10), pp. 4515-4521. Date of Electronic Publication: 2022 Mar 07. |
| DOI: |
10.1021/jacs.1c12596 |
| Abstrakt: |
The dimensional reduction of solids into smaller fragments provides a route to achieve new physical properties and gain deeper insight into the extended parent structures. Here, we report the synthesis of CuTOTP-OR (TOTP n - = 2,3,6,7-tetraoxidotriphenylene), a family of copper-based macrocycles that resemble truncated fragments of the conductive two-dimensional (2D) metal-organic framework Cu 3 (HHTP) 2 (HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene). The planar metal-organic macrocycles self-assemble into ordered nanotubes with internal diameters of ∼2 nm and short interlayer distances of ∼3.20 Å. Strong π-π stacking interactions between macrocycles facilitate out-of-plane charge transport, and pressed pellet conductivities as high as 2(1) × 10 -3 S cm -1 are observed. Peripheral alkyl functionalization enhances solution processability and enables the fabrication of thin-film field-effect transistor devices. Ambipolar charge transport is observed, suggesting that similar behavior may be operative in Cu 3 (HHTP) 2 . By coupling the attractive features of metal-organic frameworks with greater processability, these macrocycles enable facile device integration and a more nuanced understanding of out-of-plane charge transport in 2D conductive metal-organic frameworks. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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