Exchange of coordinated carboxylates with azolates as a route to obtain a microporous zinc-azolate framework.

Autor: Fahy KM; International Institute for Nanotechnology and Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA. timur.islamoglu@northwestern.edu., Mian MR; International Institute for Nanotechnology and Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA. timur.islamoglu@northwestern.edu., Wasson MC; International Institute for Nanotechnology and Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA. timur.islamoglu@northwestern.edu., Son FA; International Institute for Nanotechnology and Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA. timur.islamoglu@northwestern.edu., Islamoglu T; International Institute for Nanotechnology and Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA. timur.islamoglu@northwestern.edu., Farha OK; International Institute for Nanotechnology and Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA. timur.islamoglu@northwestern.edu.; Department of Chemical & Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2022 Mar 24; Vol. 58 (25), pp. 4028-4031. Date of Electronic Publication: 2022 Mar 24.
DOI: 10.1039/d2cc00925k
Abstrakt: Metal-organic frameworks (MOFs) containing open metal sites are advantageous for wide applications. Here, carboxylate linkers are replaced with triazolate coordination in pre-formed Zn-MOF-74 via solvent-assisted linker exchange (SALE) to prepare the novel NU-250, within the known hexagonal channel-based MAF-X25 series that has not previously been synthesized de novo .
Databáze: MEDLINE
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