Experimental and Simulation Studies on Nonwoven Polypropylene-Nitrile Rubber Blend: Recycling of Medical Face Masks to an Engineering Product.

Autor: Varghese P J G; Department of Metallurgical and Materials Engineering, Indian Institute of Technology Patna (IIT P), Patna 801106, Bihar, India.; Materials Science and NanoEngineering Lab, Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology (CUSAT), Kochi 682022, Kerala, India., David DA; Materials Science and NanoEngineering Lab, Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology (CUSAT), Kochi 682022, Kerala, India.; Department of Applied Chemistry, Cochin University of Science and Technology (CUSAT), Kochi 682022, Kerala, India., Karuth A; Department of Coatings and Polymeric Materials, North Dakota State University, Fargo, North Dakota 58105, United States., Manamkeri Jafferali JF; Materials Science and NanoEngineering Lab, Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology (CUSAT), Kochi 682022, Kerala, India., P M SB; Department of Applied Chemistry, Cochin University of Science and Technology (CUSAT), Kochi 682022, Kerala, India., George JJ; Materials Science and NanoEngineering Lab, Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology (CUSAT), Kochi 682022, Kerala, India., Rasulev B; Department of Coatings and Polymeric Materials, North Dakota State University, Fargo, North Dakota 58105, United States., Raghavan P; Materials Science and NanoEngineering Lab, Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology (CUSAT), Kochi 682022, Kerala, India.; Department of Materials Engineering and Convergence Technology, Gyeongsang National University, 501 Jinju-daero, Jinju 52828, Republic of Korea.
Jazyk: angličtina
Zdroj: ACS omega [ACS Omega] 2022 Jan 18; Vol. 7 (6), pp. 4791-4803. Date of Electronic Publication: 2022 Jan 18 (Print Publication: 2022).
DOI: 10.1021/acsomega.1c04913
Abstrakt: The battle against the COVID-19 pandemic counters the waste management system, as billions of single-use face masks are used per day all over the world. Proper disposal of used face masks without jeopardizing the health and the environment is a challenge. Herein, a novel method for recycling of medical face masks has been studied. This method incorporates the nonwoven polypropylene (PP) fiber, which is taken off from the mask after disinfecting it, with acrylonitrile butadiene rubber (NBR) using maleic anhydride as the compatibilizer, which results in a PP-NBR blend with a high percentage economy. The PP-NBR blends show enhanced thermomechanical properties among which, 70 wt % PP content shows superior properties compared to other composites with 40, 50, and 60 wt % of PP. The fully Atomistic simulation of PP-NBR blend with compatibilizer shows an improved tensile and barrier properties, which is in good agreement with the experimental studies. The molecular dynamics simulation confirms that the compatibility between non-polar PP and polar NBR phases are vitally important for increasing the interfacial adhesion and impeding the phase separation.
Competing Interests: The authors declare no competing financial interest.
(© 2022 The Authors. Published by American Chemical Society.)
Databáze: MEDLINE