| Autor: |
Rahman T; Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, Oregon 97331, United States., Martin NP; Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, Oregon 97331, United States., Jenkins JK; School of Chemical, Biological, and Environmental Engineering, 116 Johnson Hall, 105 SW 26th St. Corvallis, Oregon 97331, United States., Elzein R; School of Chemical, Biological, and Environmental Engineering, 116 Johnson Hall, 105 SW 26th St. Corvallis, Oregon 97331, United States., Fast DB; Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, Oregon 97331, United States., Addou R; School of Chemical, Biological, and Environmental Engineering, 116 Johnson Hall, 105 SW 26th St. Corvallis, Oregon 97331, United States., Herman GS; School of Chemical, Biological, and Environmental Engineering, 116 Johnson Hall, 105 SW 26th St. Corvallis, Oregon 97331, United States., Nyman M; Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, Oregon 97331, United States. |
| Abstrakt: |
Synthesizing functional materials from water contributes to a sustainable energy future. On the atomic level, water drives complex metal hydrolysis/condensation/speciation, acid-base, ion pairing, and solvation reactions that ultimately direct material assembly pathways. Here, we demonstrate the importance of Nb-polyoxometalate (Nb-POM) speciation in enabling deposition of Nb 2 O 5 , LiNbO 3 , and (Na, K)NbO 3 (KNN) from high-concentration solutions, up to 2.5 M Nb for Nb 2 O 5 and ∼1 M Nb for LiNbO 3 and KNN. Deposition of KNN from 1 M Nb concentration represents a potentially important advancment in lead-free piezoelectrics, an application that requires thick films. Solution characterization via small-angle X-ray scattering and Raman spectroscopy described the speciation for all precursor solutions as the [H x Nb 24 O 72 ] ( x -24) POM, as did total pair distribution function analyses of X-ray scattering of amorphous gels prior to conversion to oxides. The tendency of the Nb 24 -POM to form extended networks without crystallization leads to conformal and well-adhered films. The films were characterized by X-ray diffraction, atomic force microscopy, scanning electron microscopy, ellipsometry, and X-ray photoelectron spectroscopy. As a strategy to convert aqueous deposition solutions from {Nb 10 }-POMs to {Nb 24 }-POMs, we devised a general procedure to produce doped Nb 2 O 5 thin films including Ca, Ag, and Cu doping. |
