Crystal structure and Hirshfeld surface analysis of 5-acetyl-3-amino-6-methyl- N -phenyl-4-[( E )-2-phenyl-ethen-yl]thieno[2,3- b ]pyridine-2-carbox-amide.

Autor: Mohamed SK; Chemistry and Environmental Division, Manchester Metropolitan University, Manchester, M1 5GD, England.; Chemistry Department, Faculty of Science, Minia University, 61519 El-Minia, Egypt., Bakhite EA; Chemistry Department, Faculty of Science, Assiut University, 71516 Assiut, Egypt., Çelikesir ST; Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey., Abdu-Allah HHM; Pharmaceutical Chemistry Department, Faculty of Pharmacy, Assiut University, Assiut, Egypt., Akkurt M; Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey., Ibrahim OF; Chemistry Department, Faculty of Science, Assiut University, 71516 Assiut, Egypt., Mague JT; Department of Chemistry, Tulane University, New Orleans, LA 70118, USA., Al-Waleedy SAH; Department of Chemistry, Faculty of Science, Taiz University, Taiz, Yemen.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2022 Jan 28; Vol. 78 (Pt 2), pp. 225-230. Date of Electronic Publication: 2022 Jan 28 (Print Publication: 2022).
DOI: 10.1107/S2056989022000743
Abstrakt: The asymmetric unit of the title compound, C 25 H 21 N 3 O 2 S, comprises four mol-ecules. Their conformations differ primarily in the orientations of the styryl and the N -phenyl-carboxamido groups. In the crystal, inter-molecular N-H⋯N, C-H⋯O and C-H⋯S hydrogen-bonding contacts as well a C-H⋯π(ring) inter-actions lead to the formation of a layer structure parallel to (010). Hirshfeld surface analysis revealed that H⋯H inter-actions represent the main contributions to the crystal packing.
(© Mohamed et al. 2022.)
Databáze: MEDLINE
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