Heteroleptic Tripalladium(II) Cages.

Autor: Findlay JA; Research School of Chemistry, Australian National University, Canberra, ACT, 2600, Australia., Patil KM; MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Physical and Chemical Sciences, University of Canterbury, Christchurch, 8041, New Zealand., Gardiner MG; Research School of Chemistry, Australian National University, Canberra, ACT, 2600, Australia., MacDermott-Opeskin HI; Research School of Chemistry, Australian National University, Canberra, ACT, 2600, Australia., O'Mara ML; Research School of Chemistry, Australian National University, Canberra, ACT, 2600, Australia., Kruger PE; MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Physical and Chemical Sciences, University of Canterbury, Christchurch, 8041, New Zealand., Preston D; Research School of Chemistry, Australian National University, Canberra, ACT, 2600, Australia.
Jazyk: angličtina
Zdroj: Chemistry, an Asian journal [Chem Asian J] 2022 Mar 14; Vol. 17 (6), pp. e202200093. Date of Electronic Publication: 2022 Feb 21.
DOI: 10.1002/asia.202200093
Abstrakt: There is a concerted attempt to develop self-assembled metallo-cages of greater structural complexity, and heteroleptic Pd II cages are emerging as prime candidates in these efforts. Most of these are dinuclear: few examples of higher nuclearity have been reported. We demonstrate here a robust method for the formation of tripalladium(II) cages from the 2 : 3 : 3 combination of a tritopic ligand, Pd II , and a selection of ditopic ligands of the correct size and geometry.
(© 2022 Wiley-VCH GmbH.)
Databáze: MEDLINE
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