Phase Diagram for Twinning Superlattice Te-Doped GaAs Nanowires.

Autor: Ghukasyan A; Department of Engineering Physics, McMaster University, Hamilton, Ontario, Canada L8S4L7., Goktas NI; Department of Engineering Physics, McMaster University, Hamilton, Ontario, Canada L8S4L7., Dubrovskii VG; Faculty of Physics, St. Petersburg State University, Universitetskaya Emb. 13B, 199034 St. Petersburg, Russia., LaPierre RR; Department of Engineering Physics, McMaster University, Hamilton, Ontario, Canada L8S4L7.
Jazyk: angličtina
Zdroj: Nano letters [Nano Lett] 2022 Feb 09; Vol. 22 (3), pp. 1345-1349. Date of Electronic Publication: 2022 Jan 28.
DOI: 10.1021/acs.nanolett.1c04680
Abstrakt: Twinning superlattices (TSLs) are a growing class of semiconductor structures proposed as a means of phonon and optical engineering in nanowires (NWs). In this work, we examine TSL formation in Te-doped GaAs NWs grown by a self-assisted vapor-liquid-solid mechanism (with a Ga droplet as the seed particle), using selective-area molecular beam epitaxy. In these NWs, the TSL structure is comprised of alternating zincblende twins, whose formation is promoted by the introduction of Te dopants. Using transmission electron microscopy, we investigated the crystal structure of NWs across various growth conditions (V/III flux ratio, temperature), finding periodic TSLs only at the low V/III flux ratio of 0.5 and intermediate growth temperatures of 492 to 537 °C. These results are explained by a kinetic growth model based on the diffusion flux feeding the Ga droplet.
Databáze: MEDLINE