| Autor: |
Keerthisinghe N; Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA., Christian MS; Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA., Berseneva AA; Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA., Morrison G; Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA., Klepov VV; Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA., Smith MD; Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA., Zur Loye HC; Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA. |
| Abstrakt: |
The solvothermal synthesis, structure determination and optical characterization of five new metastable halometallate compounds, [1,10-phenH][Pb 3.5 I 8 ] ( 1 ), [1,10-phenH 2 ][Pb 5 I 12 ]·(H 2 O) ( 2 ), [1,10-phen][Pb 2 I 4 ] ( 3 ), [1,10-phen] 2 [Pb 5 Br 10 ] ( 4 ) and [1,10-phenH][SbI 4 ]·(H 2 O) ( 5 ), are reported. The materials exhibit rich structural diversity and exhibit structural dimensionalities that include 1D chains, 2D sheets and 3D frameworks. The optical spectra of these materials are consistent with bandgaps ranging from 2.70 to 3.44 eV. We show that the optical behavior depends on the structural dimensionality of the reported materials, which are potential candidates for semiconductor applications. |
