Manufacturing of macroporous cellulose monolith from green macroalgae and its application for wastewater treatment.

Autor: Salim MH; Materials Science, Energy and Nano-engineering (MSN) Department, Mohammed VI Polytechnic University (UM6P), Lot 660 - Hay Moulay Rachid, 43150, Ben Guerir, Morocco., Kassab Z; Materials Science, Energy and Nano-engineering (MSN) Department, Mohammed VI Polytechnic University (UM6P), Lot 660 - Hay Moulay Rachid, 43150, Ben Guerir, Morocco. Electronic address: zineb.kassab@um6p.ma., Ablouh EH; Materials Science, Energy and Nano-engineering (MSN) Department, Mohammed VI Polytechnic University (UM6P), Lot 660 - Hay Moulay Rachid, 43150, Ben Guerir, Morocco., Sehaqui H; Materials Science, Energy and Nano-engineering (MSN) Department, Mohammed VI Polytechnic University (UM6P), Lot 660 - Hay Moulay Rachid, 43150, Ben Guerir, Morocco., Aboulkas A; Laboratoire des procédés chimiques et matériaux appliqués (LPCMA), Faculté polydisciplinaire de Béni-Mellal, Université Sultan Moulay Slimane, BP 592, 23000 Béni-Mellal, Morocco., Bouhfid R; Composites and Nanocomposites Center (CNC), Moroccan Foundation for Advanced Science, Innovation and Research (MAScIR), Rabat Design Center, Rue Mohamed El Jazouli, Madinat El Irfane, 10100 Rabat, Morocco., Qaiss AEK; Composites and Nanocomposites Center (CNC), Moroccan Foundation for Advanced Science, Innovation and Research (MAScIR), Rabat Design Center, Rue Mohamed El Jazouli, Madinat El Irfane, 10100 Rabat, Morocco., El Achaby M; Materials Science, Energy and Nano-engineering (MSN) Department, Mohammed VI Polytechnic University (UM6P), Lot 660 - Hay Moulay Rachid, 43150, Ben Guerir, Morocco. Electronic address: mounir.elachaby@um6p.ma.
Jazyk: angličtina
Zdroj: International journal of biological macromolecules [Int J Biol Macromol] 2022 Mar 01; Vol. 200, pp. 182-192. Date of Electronic Publication: 2022 Jan 04.
DOI: 10.1016/j.ijbiomac.2021.12.153
Abstrakt: Enormous interest in using marine biomass as a sustainable resource for water treatment has been manifested over the past few decades. Herein, the objective was to investigate the possible use of green macroalgae (Codium tomentosum) for cellulose-based foam production through a versatile and convenient process. Macroporous cellulose monolith was prepared from cellulose hydrogel using freeze-drying process, resulting in a mechanically rigid monolith with a high swelling ratio. The as-produced spongy-like porous cellulosic material was used as bio-sorbent for wastewater treatment, particularly for removing methylene blue (MB) dye from concentrated aqueous solution. The adsorption capacity of MB was subsequently studied, and the effect of adsorption process parameters was determined in a controlled batch system. From the kinetic studies, it was found that the adsorption equilibrium was reached within 660 min. Furthermore, the analysis of the adsorption kinetics reveals that the data could be fitted by a pseudo-second order model, while the adsorption isotherm could be described by Langmuir isotherm model. The maximum adsorption capacity was found to be 454 mg/g. The findings suggested that the produced cellulose monolith could be used as a sustainable adsorbent for water treatment.
(Copyright © 2022 Elsevier B.V. All rights reserved.)
Databáze: MEDLINE