| Autor: |
Lavrič G; Pulp and Paper Institute, Bogišićeva 8, 1000 Ljubljana, Slovenia., Zamljen A; Department of Catalysis and Chemical Reaction Engineering, National Institute of Chemistry, Hajdrihova 19, 1001 Ljubljana, Slovenia., Juhant Grkman J; Pulp and Paper Institute, Bogišićeva 8, 1000 Ljubljana, Slovenia., Jasiukaitytė-Grojzdek E; Department of Catalysis and Chemical Reaction Engineering, National Institute of Chemistry, Hajdrihova 19, 1001 Ljubljana, Slovenia., Grilc M; Department of Catalysis and Chemical Reaction Engineering, National Institute of Chemistry, Hajdrihova 19, 1001 Ljubljana, Slovenia., Likozar B; Department of Catalysis and Chemical Reaction Engineering, National Institute of Chemistry, Hajdrihova 19, 1001 Ljubljana, Slovenia., Gregor-Svetec D; Faculty of Natural Sciences and Engineering, University of Ljubljana, Snežniška 5, 1000 Ljubljana, Slovenia., Vrabič-Brodnjak U; Faculty of Natural Sciences and Engineering, University of Ljubljana, Snežniška 5, 1000 Ljubljana, Slovenia. |
| Abstrakt: |
The aim of the study was to isolate lignin from organosolv, beech tree ( Fagus sylvatica ), and Japanese knotweed ( Reynoutria japonica ), to use it for paper surface and to replace part of the non-renewable product resources with bio-based ones. A total of nine coated samples with different lignin formulations and starch were compounded, prepared, and evaluated. The basic (grammage, thickness, specific density), mechanical (elongation at break, tensile, burst and tear indices), and barrier properties (contact angle, water penetration, water vapour permeability, kit test) of the coated papers were investigated. The analysis showed no significant difference in tensile properties between uncoated and coated samples. Furthermore, the decrease in water vapour transmission rate and the lower contact angle for coated samples were nevertheless confirmed. The novel coating materials show promising products with very good barrier properties. Finally, the correlation between structural, morphological, and (other) natural lignin-based factors was revealed, highlighting the importance of parameters such as the equivalence ratio of aliphatic and phenolic hydroxyl groups or the average molecular weight. Tuning functionality by design could optimise performance in the future. |
