| Autor: |
Sønsteby HH; Department of Chemistry, University of Oslo, Blindern, 0315 Oslo, Norway. henrik.sonsteby@kjemi.uio.no., Killi VAK; Department of Chemistry, University of Oslo, Blindern, 0315 Oslo, Norway. henrik.sonsteby@kjemi.uio.no., Rykkje LM; Department of Chemistry, University of Oslo, Blindern, 0315 Oslo, Norway. henrik.sonsteby@kjemi.uio.no., Bickford JR; U.S. Army Research Laboratory, 2800 Powder Mill Rd., Adelphi, Maryland 20783, USA., Martin EG; U.S. Army Research Laboratory, 2800 Powder Mill Rd., Adelphi, Maryland 20783, USA., Hoffman RC; U.S. Army Research Laboratory, 2800 Powder Mill Rd., Adelphi, Maryland 20783, USA., Nilsen O; Department of Chemistry, University of Oslo, Blindern, 0315 Oslo, Norway. henrik.sonsteby@kjemi.uio.no. |
| Abstrakt: |
Toxic Pb-containing piezo-, pyro- and ferroelectrics continue to dominate the market even though they were banned from use in consumer products more than a decade ago. There is a strong need for sustainable alternatives, but the lack of facile synthesis routes for thin films exhibiting suitable functional properties have limited the transition from Pb workhorse materials like Pb(Zr,Ti)O 3 and Pb(Mg,Nb)O 3 - PbTiO 3 . Atomic layer deposition has proven capable of the deposition of possible successors, such as LiNbO 3 , (K,Na)NbO 3 and K(Ta,Nb)O 3 , albeit with limited control due to water reservoir effects resulting from the hygroscopicity of intermediate products. In this article, we show that replacing H 2 O with O 3 in the deposition of complex alkali oxides provides an alternative and much more controlled process. We exemplify this by deposition of crystalline K(Ta,Nb)O 3 with high compositional control and over a larger composition range than previously reported. This opens new doors to a simplified synthesis of polar functional lead-free alternatives. |
