Dinitrogen-derived (diarylboryl)diazenido complexes with differing coordination to the thallium cation.

Autor:	Bouammali A; LCC-CNRS, Université de Toulouse, CNRS, UPS, 205 route de Narbonne, BP44099, F-31077 Toulouse cedex 4, France. antoine.simonneau@lcc-toulouse.fr., Coffinet A; LCC-CNRS, Université de Toulouse, CNRS, UPS, 205 route de Narbonne, BP44099, F-31077 Toulouse cedex 4, France. antoine.simonneau@lcc-toulouse.fr., Vendier L; LCC-CNRS, Université de Toulouse, CNRS, UPS, 205 route de Narbonne, BP44099, F-31077 Toulouse cedex 4, France. antoine.simonneau@lcc-toulouse.fr., Simonneau A; LCC-CNRS, Université de Toulouse, CNRS, UPS, 205 route de Narbonne, BP44099, F-31077 Toulouse cedex 4, France. antoine.simonneau@lcc-toulouse.fr.
Jazyk:	angličtina
Zdroj:	Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2022 Jul 19; Vol. 51 (28), pp. 10697-10701. Date of Electronic Publication: 2022 Jul 19.
DOI:	10.1039/d1dt03905a
Abstrakt:	To prepare N 2 -derived cationic boryldiazenido-tungsten complexes as models of semimetallic metal-borinium frustrated Lewis pairs activating N 2 , we have attempted halide abstraction from trans -(diarylboryl)diazenido-halo-tungsten complexes. Reactions with Tl + led to adducts in which coordination of the cation differs depending on the boryldiazenide substituents and the ancillary ligand. Chloride scavenging was not observed.
Databáze:	MEDLINE
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