| Autor: |
Nimax PR; National Center for Biomolecular Research, Masaryk University, Kamenice 5, CZ-62500 Brno, Czechia. patricknimax@mail.muni.cz., Rotthowe N; Department of Chemistry, University of Konstanz, Universitätsstr. 10, 788457 Konstanz, Germany., Zoller F; Department of Chemistry, Ludwig-Maximilian University, Butenandstr. 5-13, 81377 Munich, Germany., Blockhaus T; Department of Chemistry, Ludwig-Maximilian University, Butenandstr. 5-13, 81377 Munich, Germany., Wagner F; Department of Physics, TU Munich, James-Franck Str., 85748 Garching, Germany., Fattakhova D; Electrochemical Storage Department, IEK-1, Forschungszentrum Julich, Wilhelm-Johnen-Str., 52425 Juelich, Germany., Sünkel K; Department of Chemistry, Ludwig-Maximilian University, Butenandstr. 5-13, 81377 Munich, Germany. |
| Abstrakt: |
Compounds of the 5 amino (ATCC) and 5 nitro 1,2,3,4 tetracyanocyclopentadienide (NTCC) ligand with iron(II) and iron(III), silver(I) and potassium(I) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mößbauer spectroscopy as well as UV-Vis spectroscopy. The investigation sheds light on the free radical activity in non- as well as transition metal compounds, and shows signs of photoinduced electron transfer in transition metal compounds of the ligands. We characterized silver(I) and potassium compounds of the compounds via X-ray diffraction, with one of the structures exhibiting a porous coordination polymer. |
