C-H activation by immobilized heterogeneous photocatalysts.

Autor: Choi I; Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077, Göttingen, Germany.; Wöhler Research Institute for Sustainable Chemistry (WISCh), Georg-August-Universität Göttingen, Tammanstraße 2, 37077, Göttingen, Germany., Struwe J; Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077, Göttingen, Germany.; Wöhler Research Institute for Sustainable Chemistry (WISCh), Georg-August-Universität Göttingen, Tammanstraße 2, 37077, Göttingen, Germany., Ackermann L; Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077, Göttingen, Germany. Lutz.Ackermann@chemie.uni-goettingen.de.; Wöhler Research Institute for Sustainable Chemistry (WISCh), Georg-August-Universität Göttingen, Tammanstraße 2, 37077, Göttingen, Germany. Lutz.Ackermann@chemie.uni-goettingen.de.
Jazyk: angličtina
Zdroj: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology [Photochem Photobiol Sci] 2021 Dec; Vol. 20 (12), pp. 1563-1572. Date of Electronic Publication: 2021 Nov 16.
DOI: 10.1007/s43630-021-00132-9
Abstrakt: During the last decades, the merger of photocatalysis with transition metal chemistry has been surfaced as a sustainable tool in modern molecular syntheses. This Account highlights major advances in synergistic photo-enabled C‒H activations. Inspired by our homogenous ruthenium- and copper-catalyzed C‒H activations in the absence of an exogenous photosensitizer, this Account describes the recent progress on heterogeneous photo-induced C‒H activation enabled by immobilized hybrid catalysts until September 2021, with a topical focus on recyclability as well as robustness of the heterogeneous photocatalyst.
(© 2021. The Author(s).)
Databáze: MEDLINE
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