Crystal structure of N '-[2-(benzo[ d ]thia-zol-2-yl)acet-yl]benzohydrazide, an achiral compound crystallizing in space group P 1 with Z = 1.

Autor: Azzam RA; Chemistry Department, Faculty of Science, Helwan University, Cairo, Egypt., Elgemeie GH; Chemistry Department, Faculty of Science, Helwan University, Cairo, Egypt., Seif MM; Chemistry Department, Faculty of Science, Helwan University, Cairo, Egypt., Jones PG; Institut für Anorganische und Analytische Chemie, Technische Universität Braunschweig, Hagenring 30, D-38106 Braunschweig, Germany.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2021 Aug 03; Vol. 77 (Pt 9), pp. 891-894. Date of Electronic Publication: 2021 Aug 03 (Print Publication: 2021).
DOI: 10.1107/S2056989021007672
Abstrakt: In the mol-ecule of the title compound, C 16 H 13 N 3 O 2 S, one hydrazinic nitro-gen atom is essentially planar, but the other is slightly pyramidalized. The torsion angle about the hydrazinic bond is 66.44 (15)°. Both hydrazinic hydrogen atoms lie anti-periplanar to the oxygen of the adjacent carbonyl group. The mol-ecular packing is a layer structure determined by two classical hydrogen bonds, N-H⋯O=C and N-H⋯N thia-zole . The space group is P 1 with Z = 1, which is unusual for an achiral organic compound.
(© Azzam et al. 2021.)
Databáze: MEDLINE
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