Halogen bonding effect on electrochemical anion oxidation in ionic liquids.
| Autor: | Alvarez MS; Université de Paris - Laboratoire d'Electrochimie Moléculaire, CNRS, F-75006 Paris, France. claire.fave@u-paris.fr., Houzé C; Université de Paris - Laboratoire d'Electrochimie Moléculaire, CNRS, F-75006 Paris, France. claire.fave@u-paris.fr., Groni S; Université de Paris - Laboratoire d'Electrochimie Moléculaire, CNRS, F-75006 Paris, France. claire.fave@u-paris.fr., Schöllhorn B; Université de Paris - Laboratoire d'Electrochimie Moléculaire, CNRS, F-75006 Paris, France. claire.fave@u-paris.fr., Fave C; Université de Paris - Laboratoire d'Electrochimie Moléculaire, CNRS, F-75006 Paris, France. claire.fave@u-paris.fr. |
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| Jazyk: | angličtina |
| Zdroj: | Organic & biomolecular chemistry [Org Biomol Chem] 2021 Sep 15; Vol. 19 (35), pp. 7587-7593. Date of Electronic Publication: 2021 Sep 15. |
| DOI: | 10.1039/d1ob01031j |
| Abstrakt: | Three Ionic liquids (ILs) based on an imidazolium core have been compared and used as solvents for the oxidation of various anions. Electrochemical experiments as well as NMR titrations and X-ray diffraction analyses unambiguously confirm the crucial role of non-covalent halogen bonding on the oxidation potentials and consequently the electrochemical window of the respective ILs. |
| Databáze: | MEDLINE |
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