Synthesis and crystallographic studies of 2-(di-phenyl-phosphino-thio-yl)-2-(3-oxobut-1-en-yl)ferrocene.

Autor: Bandyopadhyay U; CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse, UPS, INPT, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France., Sundararaju B; Department of Chemistry, Indian Institute of Technology Kanpur, Uttar Pradesh, India., Poli R; CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse, UPS, INPT, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France., Manoury E; CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse, UPS, INPT, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France., Daran JC; CNRS, LCC (Laboratoire de Chimie de Coordination), Université de Toulouse, UPS, INPT, 205 Route de Narbonne, F-31077 Toulouse Cedex 4, France.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2021 Jul 30; Vol. 77 (Pt 8), pp. 853-856. Date of Electronic Publication: 2021 Jul 30 (Print Publication: 2021).
DOI: 10.1107/S205698902100760X
Abstrakt: As a follow-up to our research on the chemistry of disubstituted ferrocene derivatives, the synthesis and the structure of the title compound, 2-(di-phenyl-phosphino-thio-yl)-2-(3-oxobut-1-en-yl)ferrocene, [Fe(C 5 H 5 )(C 21 H 18 OPS)], are described. The mol-ecule is built up from a ferrocene unit disubstituted by an S-protected di-phenyl-phosphine group and by a methyl-vinyl-ketone chain. The crystal structure features weak C-H⋯O and C-H⋯S inter-actions, which build a two-dimensional network. This structure is compared to that of the related disubstituted di-phenyl-phosphino ferrocene.
(© Bandyopadhyay et al. 2021.)
Databáze: MEDLINE
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