Polypyrrole-Gold nanocomposites as a promising photothermal agent: Preparation, characterization and cytotoxicity study.

Autor: Ibrahim JS; Department of Laser Applications in Metrology, Photochemistry and Agriculture (LAMPA), National Institute of Laser Enhanced Sciences (NILES), Cairo University, Cairo, Egypt. Electronic address: jilansaber@pg.cu.edu.eg., Hanafi N; Department of Radiation Biology, National Center for Radiation Research and Technology (NCRRT), Egyptian Atomic Energy Authority, Cairo, Egypt., El-Tayeb TA; Department of Laser Applications in Metrology, Photochemistry and Agriculture (LAMPA), National Institute of Laser Enhanced Sciences (NILES), Cairo University, Cairo, Egypt., Sliem MA; Department of Laser Applications in Metrology, Photochemistry and Agriculture (LAMPA), National Institute of Laser Enhanced Sciences (NILES), Cairo University, Cairo, Egypt.
Jazyk: angličtina
Zdroj: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy [Spectrochim Acta A Mol Biomol Spectrosc] 2022 Jan 05; Vol. 264, pp. 120221. Date of Electronic Publication: 2021 Jul 24.
DOI: 10.1016/j.saa.2021.120221
Abstrakt: Photothermal nanomaterials with near-infrared absorption and high energy conversion efficiency have recently attracted significant interest. Polypyrrole-gold nanocomposites (PPy-Au NCs) as photothermal nanoagents are synthesized using ex-situ polymerization method of the modified pyrrole monomers. Microscopic and spectroscopic characterization techniques are used to reveal the surface structure, composition variation and photoelectric properties of PPy-Au NCs, gold nanorods (Au NRs) and polypyyrole nanoparticles (PPy NPs). Their cytotoxic effects on the viability of Ehrlich Ascites Carcinoma cells in the dark are demonstrated. The surface coating of Au NRs with PPy NPs shows an enhancement in the photothermal efficiency of the proposed photothermal nanoagent. The photothermal conversion of nanomaterials are examined using polarized polychromatic incoherent low-energy light source (the energy density of the light is 2.4 J/cm 2 per minute and the specific power density is 40 mW/cm 2 ).
Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
(Copyright © 2021 Elsevier B.V. All rights reserved.)
Databáze: MEDLINE