| Autor: |
Zhang MX; Lawrence Livermore National Laboratory, 7000 East Ave, Livermore, CA 94550, USA., Zuckerman NB; Lawrence Livermore National Laboratory, 7000 East Ave, Livermore, CA 94550, USA., Pagoria PF; Lawrence Livermore National Laboratory, 7000 East Ave, Livermore, CA 94550, USA., Steele BA; Lawrence Livermore National Laboratory, 7000 East Ave, Livermore, CA 94550, USA., Kuo IF; Lawrence Livermore National Laboratory, 7000 East Ave, Livermore, CA 94550, USA., Imler GH; Naval Research Laboratory, 4555 Overlook Ave, Washington, DC 20375, USA., Parrish D; Naval Research Laboratory, 4555 Overlook Ave, Washington, DC 20375, USA. |
| Abstrakt: |
Mono- and dinitro-BN-naphthalenes, i.e., 1-nitro-, 3-nitro-, 1,6-dinitro-, 3,6-dinitro-, and 1,8-dinitro-BNN, were generated in the nitration of 9,10-BN-naphthalene (BNN), a boron-nitrogen (BN) bond-embedded naphthalene, with AcONO 2 and NO 2 BF 4 in acetonitrile. The nitrated products were isolated and characterized by NMR, GC-MS, IR, and X-ray single crystallography. The effects of the nitration on the electron density and aromaticity of BNN were evaluated by B-11 NMR analysis and HOMA calculations. |
