| Autor: |
Gera T; Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, Karnataka, India., Sebastian KL; Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, Karnataka, India. |
| Jazyk: |
angličtina |
| Zdroj: |
The Journal of chemical physics [J Chem Phys] 2021 Jul 07; Vol. 155 (1), pp. 014902. |
| DOI: |
10.1063/5.0056506 |
| Abstrakt: |
We consider the escape of a particle trapped in a metastable potential well and acted upon by two noises. One of the noises is thermal and the other is Poisson white noise, which is non-Gaussian. Using path integral techniques, we find an analytic solution to this generalization of the classic Kramers barrier crossing problem. Using the "barrier climbing" path, we calculate the activation exponent. We also derive an approximate expression for the prefactor. The calculated results are compared with the simulations, and a good agreement between the two is found. Our results show that, unlike in the case of thermal noise, the rate depends not just on the barrier height but also on the shape of the whole barrier. A comparison between the simulations and the theory also shows that a better approximation for the prefactor is needed for agreement for all values of the parameters. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
|
