| Autor: |
Huchenski BSN; Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4R2, Canada. aspeed@dal.ca., Speed AWH; Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4R2, Canada. aspeed@dal.ca. |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2021 Jul 20; Vol. 57 (58), pp. 7128-7131. |
| DOI: |
10.1039/d1cc01943k |
| Abstrakt: |
Upon treatment with sulfur hexafluoride, alkali metal diphenyl or dicyclohexyl phosphides are oxidized within seconds to tetraphenyl or tetracyclohexyl diphosphines. When bulky di-tert-butylphosphide is employed, fluorophosphine intermediates are detected. This is the first reported reaction of sulfur hexafluoride with metal phosphides, and a rare example of reactivity of sulfur hexafluoride at ambient temperature. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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