| Autor: |
Melo RPF; Universidade Federal Rural do Semi-Árido, Campus Pau dos Ferros, Road BR-226, no number, Pau dos Ferros - RN, 59900-000, Brazil E-mail: ricardo.melo@ufersa.edu.br., Carmo SKS; Universidade Federal Rural do Semi-Árido, Campus Pau dos Ferros, Road BR-226, no number, Pau dos Ferros - RN, 59900-000, Brazil E-mail: ricardo.melo@ufersa.edu.br., Barros ELB; Centro de Tecnologia - Departamento de Engenharia Química, Programa de Pós-Graduação em Engenharia Química, Universidade Federal do Rio Grande do Norte, Campus Universitário, Av. Senador Salgado Filho 3000, Natal-RN, 59072-970, Brazil., Câmara AG; Centro de Tecnologia - Departamento de Engenharia Química, Programa de Pós-Graduação em Engenharia Química, Universidade Federal do Rio Grande do Norte, Campus Universitário, Av. Senador Salgado Filho 3000, Natal-RN, 59072-970, Brazil., Nunes SKS; Centro de Tecnologia - Departamento de Engenharia Química, Programa de Pós-Graduação em Engenharia Química, Universidade Federal do Rio Grande do Norte, Campus Universitário, Av. Senador Salgado Filho 3000, Natal-RN, 59072-970, Brazil., Barros Neto EL; Centro de Tecnologia - Departamento de Engenharia Química, Programa de Pós-Graduação em Engenharia Química, Universidade Federal do Rio Grande do Norte, Campus Universitário, Av. Senador Salgado Filho 3000, Natal-RN, 59072-970, Brazil. |
| Abstrakt: |
The textile industry is one of the main generators of industrial effluent due to the large volumes of water containing a wide variety of pollutants, including dyes. Thus, the present study aimed to remove the Disperse Blue 56 dye present in synthetic textile effluent using ionic flocculation through surfactant flocs produced from animal/vegetable fat, assessing the system at different surfactant concentrations and temperatures. The process kinetics, adsorption mechanism and equilibrium were evaluated. The results show that the kinetics was better described by the Elovich model when compared to pseudo-first order and pseudo-second order models, indicating that chemical adsorption occurs during the process. The study of the adsorption mechanism obtained lower outer layer diffusivities than their intra-particle counterparts, demonstrating that the dye transport to the surfactant floc is controlled through the outer layer. The Langmuir isotherm was suitable for equilibrium data and the separation factor calculated showed that the isotherm is classified as favorable. Dye removal efficiency reached 87% after 360 minutes of contact between the effluent and the surfactant flocs, indicating that ionic flocculation is an efficient alternative in the treatment of textile effluent containing disperse dye. |
