Charge Neutral [Cu 2 L 2 ] and [Pd 2 L 2 ] Metallocycles: Self-Assembly, Aggregation, and Catalysis.

Autor: Kołodziejski M; Faculty of Chemistry, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland.; Centre for Advanced Technologies, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 10, 61-614 Poznań, Poland., Brock AJ; School of Chemistry and Molecular Biosciences, The University of Queensland, St Lucia 4072, Queensland, Australia., Kurpik G; Faculty of Chemistry, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland.; Centre for Advanced Technologies, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 10, 61-614 Poznań, Poland., Walczak A; Faculty of Chemistry, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland.; Centre for Advanced Technologies, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 10, 61-614 Poznań, Poland., Li F; School of Science, Western Sydney University, Locked Bag 1797, Penrith New South Wales 2751, Australia., Clegg JK; School of Chemistry and Molecular Biosciences, The University of Queensland, St Lucia 4072, Queensland, Australia., Stefankiewicz AR; Faculty of Chemistry, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 8, 61-614 Poznań, Poland.; Centre for Advanced Technologies, Adam Mickiewicz University in Poznań, Uniwersytetu Poznańskiego 10, 61-614 Poznań, Poland.
Jazyk: angličtina
Zdroj: Inorganic chemistry [Inorg Chem] 2021 Jul 05; Vol. 60 (13), pp. 9673-9679. Date of Electronic Publication: 2021 Jun 11.
DOI: 10.1021/acs.inorgchem.1c00967
Abstrakt: A range of morphologically distinct metallosupramolecular Cu(II) and Pd(II) complexes has been constructed, based on the tritopic ligand 1,1',1″-(benzene-1,3,5-triyl)tris(4,4-dimethylpentane-1,3-dione) (H 3 L ). By control of the reaction conditions, it is possible to generate distinct coordination assemblies possessing either macrocyclic or polymeric structures and more importantly distinct activity in catalysis of the Suzuki-Miyaura cross-coupling.
Databáze: MEDLINE