Liquid Crystal-Mediated 3D Printing Process to Fabricate Nano-Ordered Layered Structures.

Autor: Jalili AR; School of Chemical Engineering, University of New South Wales (UNSW), Sydney 2052, New South Wales, Australia., Satalov A; Institut für Anorganische Chemie, Leibniz Universität Hannover, Callinstr. 9, Hannover 30167, Germany., Nazari S; School of Chemical Engineering, University of New South Wales (UNSW), Sydney 2052, New South Wales, Australia., Rahmat Suryanto BH; Australian Centre for Electromaterials Science, School of Chemistry, Monash University, Clayton 3800, Victoria, Australia., Sun J; School of Chemical Engineering, University of New South Wales (UNSW), Sydney 2052, New South Wales, Australia., Ghasemian MB; School of Chemical Engineering, University of New South Wales (UNSW), Sydney 2052, New South Wales, Australia., Mayyas M; School of Chemical Engineering, University of New South Wales (UNSW), Sydney 2052, New South Wales, Australia., Kandjani AE; School of Science, RMIT University, Melbourne 3001, Victoria, Australia., Sabri YM; School of Science, RMIT University, Melbourne 3001, Victoria, Australia., Mayes E; School of Science, RMIT University, Melbourne 3001, Victoria, Australia., Bhargava SK; School of Science, RMIT University, Melbourne 3001, Victoria, Australia., Araki J; Faculty of Textile Science and Technology, Shinshu University, Tokida 3-15-1, Ueda 386-8567, Nagano prefecture, Japan.; Institute for Fiber Engineering (IFES), Interdisciplinary Cluster for Cutting Edge Research (ICCER), Shinshu University, Tokida 3-15-1, Ueda 386-8567, Nagano prefecture, Japan., Zakri C; Centre de Recherche Paul Pascal-CNRS, University of Bordeaux, Pessac 33600, France., Poulin P; Centre de Recherche Paul Pascal-CNRS, University of Bordeaux, Pessac 33600, France., Esrafilzadeh D; Graduate School of Biomedical Engineering, University of New South Wales, Sydney 2031, New South Wales, Australia., Amal R; School of Chemical Engineering, University of New South Wales (UNSW), Sydney 2052, New South Wales, Australia.
Jazyk: angličtina
Zdroj: ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2021 Jun 23; Vol. 13 (24), pp. 28627-28638. Date of Electronic Publication: 2021 Jun 10.
DOI: 10.1021/acsami.1c05025
Abstrakt: The emergence of three-dimensional (3D) printing promises a disruption in the design and on-demand fabrication of smart structures in applications ranging from functional devices to human organs. However, the scale at which 3D printing excels is within macro- and microlevels and principally lacks the spatial ordering of building blocks at nanolevels, which is vital for most multifunctional devices. Herein, we employ liquid crystal (LC) inks to bridge the gap between the nano- and microscales in a single-step 3D printing. The LC ink is prepared from mixtures of LCs of nanocellulose whiskers and large sheets of graphene oxide, which offers a highly ordered laminar organization not inherently present in the source materials. LC-mediated 3D printing imparts the fine-tuning required for the design freedom of architecturally layered systems at the nanoscale with intricate patterns within the 3D-printed constructs. This approach empowered the development of a high-performance humidity sensor composed of self-assembled lamellar organization of NC whiskers. We observed that the NC whiskers that are flat and parallel to each other in the laminar organization allow facile mass transport through the structure, demonstrating a significant improvement in the sensor performance. This work exemplifies how LC ink, implemented in a 3D printing process, can unlock the potential of individual constituents to allow macroscopic printing architectures with nanoscopic arrangements.
Databáze: MEDLINE