Control of polarization in bulk ferroelectrics by mechanical dislocation imprint.

Autor: Höfling M; Department of Materials and Earth Sciences, Technical University of Darmstadt, 64287 Darmstadt, Germany., Zhou X; Department of Materials and Earth Sciences, Technical University of Darmstadt, 64287 Darmstadt, Germany., Riemer LM; Group for Ferroelectrics and Functional Oxides, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland., Bruder E; Department of Materials and Earth Sciences, Technical University of Darmstadt, 64287 Darmstadt, Germany., Liu B; Department of Materials Science and Engineering, Iowa State University, Ames, IA 50011, USA., Zhou L; Department of Materials Science and Engineering, Iowa State University, Ames, IA 50011, USA.; Ames Laboratory, U.S. Department of Energy, Ames, IA 50011, USA., Groszewicz PB, Zhuo F; Department of Materials and Earth Sciences, Technical University of Darmstadt, 64287 Darmstadt, Germany., Xu BX; Department of Materials and Earth Sciences, Technical University of Darmstadt, 64287 Darmstadt, Germany., Durst K; Department of Materials and Earth Sciences, Technical University of Darmstadt, 64287 Darmstadt, Germany., Tan X; Department of Materials Science and Engineering, Iowa State University, Ames, IA 50011, USA., Damjanovic D; Group for Ferroelectrics and Functional Oxides, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland., Koruza J; Department of Materials and Earth Sciences, Technical University of Darmstadt, 64287 Darmstadt, Germany. koruza@ceramics.tu-darmstadt.de roedel@ceramics.tu-darmstadt.de., Rödel J; Department of Materials and Earth Sciences, Technical University of Darmstadt, 64287 Darmstadt, Germany. koruza@ceramics.tu-darmstadt.de roedel@ceramics.tu-darmstadt.de.
Jazyk: angličtina
Zdroj: Science (New York, N.Y.) [Science] 2021 May 28; Vol. 372 (6545), pp. 961-964.
DOI: 10.1126/science.abe3810
Abstrakt: Defects are essential to engineering the properties of functional materials ranging from semiconductors and superconductors to ferroics. Whereas point defects have been widely exploited, dislocations are commonly viewed as problematic for functional materials and not as a microstructural tool. We developed a method for mechanically imprinting dislocation networks that favorably skew the domain structure in bulk ferroelectrics and thereby tame the large switching polarization and make it available for functional harvesting. The resulting microstructure yields a strong mechanical restoring force to revert electric field-induced domain wall displacement on the macroscopic level and high pinning force on the local level. This induces a giant increase of the dielectric and electromechanical response at intermediate electric fields in barium titanate [electric field-dependent permittivity (ε 33 ) ≈ 5800 and large-signal piezoelectric coefficient ( d 33 *) ≈ 1890 picometers/volt]. Dislocation-based anisotropy delivers a different suite of tools with which to tailor functional materials.
(Copyright © 2021 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.)
Databáze: MEDLINE
Externí odkaz:
Nepřihlášeným uživatelům se plný text nezobrazuje