13 C NMR spectra of amino-alkylphosphonic acids.

Autor: Głowacki Z; Department of Organic Chemistry, Technical University, 80-952 Gdansk 6, Poland., Topolski M; Department of Organic Chemistry, Technical University, 80-952 Gdansk 6, Poland.
Jazyk: angličtina
Zdroj: Magnetic resonance in chemistry : MRC [Magn Reson Chem] 1989 Sep; Vol. 27 (9), pp. 897-899.
DOI: 10.1002/mrc.1260270915
Abstrakt: 13 C chemical shifts and 31 P, 13 C coupling constants are reported for 20 amino-alkylphosphonic acids and two phosphonic acids. The substituent-induced chemical shifts of the phosphonate group were calculated and their non-additivity in 1-aminoalkylphosphonic acids was observed. Two stable conformers of 4-aminobutylphosphonic acid were detected by 13 C NMR.
(Copyright © 1989 John Wiley & Sons, Ltd.)
Databáze: MEDLINE