Synthetic approaches for accessing rare-earth analogues of UiO-66.

Autor: Donnarumma PR; Department of Chemistry and Biochemistry, and Centre for NanoScience Research, Concordia University, 7141 Sherbrooke St W., Montréal, QC H4B 1R6, Canada. ashlee.howarth@concordia.ca., Frojmovic S; Department of Chemistry and Biochemistry, and Centre for NanoScience Research, Concordia University, 7141 Sherbrooke St W., Montréal, QC H4B 1R6, Canada. ashlee.howarth@concordia.ca., Marino P; Department of Chemistry and Biochemistry, and Centre for NanoScience Research, Concordia University, 7141 Sherbrooke St W., Montréal, QC H4B 1R6, Canada. ashlee.howarth@concordia.ca., Bicalho HA; Department of Chemistry and Biochemistry, and Centre for NanoScience Research, Concordia University, 7141 Sherbrooke St W., Montréal, QC H4B 1R6, Canada. ashlee.howarth@concordia.ca., Titi HM; Department of Chemistry, McGill University, 801 Sherbrooke St W., Montréal, QC H3A 0B8, Canada., Howarth AJ; Department of Chemistry and Biochemistry, and Centre for NanoScience Research, Concordia University, 7141 Sherbrooke St W., Montréal, QC H4B 1R6, Canada. ashlee.howarth@concordia.ca.
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2021 Jun 22; Vol. 57 (50), pp. 6121-6124.
DOI: 10.1039/d1cc01552d
Abstrakt: Rare-earth (RE) analogues of UiO-66 with non-functionalised 1,4-benzenedicarboxylate linkers are synthesised for the first time, and a series of synthetic approaches is provided to troubleshoot the synthesis. RE-UiO-66 analogues are fully characterised, and demonstrate a high degree of crystallinity, high surface area and thermal stability, consistent with the UiO-66 archetype.
Databáze: MEDLINE