A practical method for regiocontrolled one-carbon ring contraction.

Autor: Mitcheltree MJ; Department of Chemistry, Yale University, New Haven, CT 06511, United States., Konst ZA; Department of Chemistry, Yale University, New Haven, CT 06511, United States., Herzon SB; Department of Chemistry, Yale University, New Haven, CT 06511, United States.
Jazyk: angličtina
Zdroj: Tetrahedron letters [Tetrahedron Lett] 2013 Jul 08; Vol. 69 (27-28), pp. 5634-5639. Date of Electronic Publication: 2013 Apr 17.
DOI: 10.1016/j.tet.2013.04.027
Abstrakt: A practical and efficient method for the perfluorobutanesulfonyl azide-mediated one-carbon ring contraction of cyclic enoxysilanes is described. High-yielding procedures for the elaboration of the resulting N -acyl sulfonamide products are reported.
Databáze: MEDLINE