Kinetic model of polyunsaturated fatty acids oxidation in micelles.

Autor: Pliss EM; P.G. Demidov Yaroslavl State University, Russian Federation. Electronic address: pliss@uniyar.ac.ru., Soloviev ME; Yaroslavl State Technical University, Russian Federation., Loshadkin DV; Yaroslavl State Technical University, Russian Federation., Molodochkina SV; P.G. Demidov Yaroslavl State University, Russian Federation., Kasaikina OT; N.N. Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences, Russian Federation.
Jazyk: angličtina
Zdroj: Chemistry and physics of lipids [Chem Phys Lipids] 2021 Jul; Vol. 237, pp. 105089. Date of Electronic Publication: 2021 May 10.
DOI: 10.1016/j.chemphyslip.2021.105089
Abstrakt: A kinetic model of polyunsaturated fatty acids (PUFAs) radical chain oxidation in micelles is presented, taking into account the diffusion of active intermediates between aqueous and organic phases, and its effect on the detailed mechanism of the process. The model made it possible to indirectly involve the structural changes of micelles and their kinetic characteristics by varying the actual values of the reactions rate constants. The modeling results are in good agreement with experimental data for the oxidation of methyl linoleate and linoleic acid.
(Copyright © 2021. Published by Elsevier B.V.)
Databáze: MEDLINE
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