Organic Electrosynthesis Towards Sustainability: Fundamentals and Greener Methodologies.

Autor: Cembellín S; University of Alcala, Organic and Inorganic Chemistry Department (Organic area), Campus, km 33,6 A2, 28805, Alcalá de Henares, Madrid, Spain., Batanero B; University of Alcala, Organic and Inorganic Chemistry Department (Organic area), Campus, km 33,6 A2, 28805, Alcalá de Henares, Madrid, Spain.; Instituto de Investigación Química, 'Andrés M. del Río' (IQAR) University of Alcala.
Jazyk: angličtina
Zdroj: Chemical record (New York, N.Y.) [Chem Rec] 2021 Sep; Vol. 21 (9), pp. 2453-2471. Date of Electronic Publication: 2021 May 05.
DOI: 10.1002/tcr.202100128
Abstrakt: The adoption of new measures that preserve our environment, on which our survival depends, is a necessity. Electro-organic processes are sustainable per se, by producing the activation of a substrate by electron transfer at normal pressure and room temperature. In the recent years, a highly crescent number of works on organic electrosynthesis are available. Novel strategies at the electrode are being developed enabling the construction of a great variety of complex organic molecules. However, the possibility of being scaled-up is mandatory in terms of sustainability. Thus, some electrochemical methodologies have demonstrated to report the best results in reducing pollution and saving energy. In this personal account, these methods have been compiled, being organized as follows: • Direct discharge electrosynthesis • Paired electrochemical reactions. and • Organic transformations utilizing electrocatalysis (in absence of heavy metals). Selected protocols are herein presented and discussed with representative recent examples. Final perspectives and reflections are also considered.
(© 2021 The Chemical Society of Japan & Wiley-VCH GmbH.)
Databáze: MEDLINE
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