Structure of Λ(δλλ)-[Co(en) 3 ]I 3 (I) 2 .

Autor: Kollitz MR; University of Notre Dame, Department of Chemistry and Biochemistry, 251 Nieuwland Science Hall, Notre Dame IN 46556, USA., Oliver AG; University of Notre Dame, Department of Chemistry and Biochemistry, 251 Nieuwland Science Hall, Notre Dame IN 46556, USA., Lappin AG; University of Notre Dame, Department of Chemistry and Biochemistry, 251 Nieuwland Science Hall, Notre Dame IN 46556, USA.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2021 Mar 31; Vol. 77 (Pt 4), pp. 446-449. Date of Electronic Publication: 2021 Mar 31 (Print Publication: 2021).
DOI: 10.1107/S2056989021002826
Abstrakt: The structure of tris-(ethane-1,2-di-amine-κ 2 N,N ')cobalt(III) bis-(iodide) triiodide, [Co(C 2 H 8 N 2 ) 3 ]I 3 (I) 2 , at 120 K has ortho-rhom-bic ( P 2 1 2 1 2 1 ) symmetry. The di-amine nitro-gen atoms form N-H⋯I hydrogen bonds throughout the lattice, resulting in a three-dimensional network, which involves the iodide and all atoms in the triiodide anions.
(© Kollitz et al. 2021.)
Databáze: MEDLINE
Externí odkaz: