Regioselective Arylboration of 1,3-Butadiene.

Autor: Bergmann AM; Department of Chemistry, Indiana University, 800 E Kirkwood Ave., Bloomington, IN 47405, USA., Sardini SR; Department of Chemistry, Indiana University, 800 E Kirkwood Ave., Bloomington, IN 47405, USA., Smith KB; Department of Chemistry, Indiana University, 800 E Kirkwood Ave., Bloomington, IN 47405, USA., Brown MK; Department of Chemistry, Indiana University, 800 E Kirkwood Ave., Bloomington, IN 47405, USA.
Jazyk: angličtina
Zdroj: Israel journal of chemistry [Isr J Chem] 2020 Mar; Vol. 60 (3-4), pp. 394-397. Date of Electronic Publication: 2019 Aug 21.
DOI: 10.1002/ijch.201900060
Abstrakt: A method for the regioselective 1,2-arylboration of 1,3-butadiene, a feedstock chemical, is reported. The reactions result in the formation of products that can be easily elaborated to other structures. The mechanistic details of this process are also discussed.
Databáze: MEDLINE