Influence of Modified Epoxy Resins on Peroxide Curing, Mechanical Properties and Adhesion of SBR, NBR and XNBR to Silver Wires. Part I: Application of Monoperoxy Derivative of Epoxy Resin (PO).

Autor: Chudzik J; Institute of Polymer & Dye Technology, Lodz University of Technology, 90-924 Lodz, Poland., Bieliński DM; Institute of Polymer & Dye Technology, Lodz University of Technology, 90-924 Lodz, Poland., Bratychak M; Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79-013 Lviv, Ukraine., Demchuk Y; Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79-013 Lviv, Ukraine., Astakhova O; Institute of Chemistry and Chemical Technologies, Lviv Polytechnic National University, 79-013 Lviv, Ukraine., Jędrzejczyk M; Institute of General and Ecological Chemistry, Lodz University of Technology, 90-924 Lodz, Poland., Celichowski G; Department of Materials Technology and Chemistry, Faculty of Chemistry, University of Lodz, 90-936 Lodz, Poland.
Jazyk: angličtina
Zdroj: Materials (Basel, Switzerland) [Materials (Basel)] 2021 Mar 09; Vol. 14 (5). Date of Electronic Publication: 2021 Mar 09.
DOI: 10.3390/ma14051320
Abstrakt: The research was aimed at checking the effect of monoperoxy derivative of epoxy resin (PO) on the possibility of rubber crosslinking and a subsequent adhesion of the modified rubber to silver wires. Three of the commonly industrially used rubbers were selected for the study: styrene-butadiene rubber (SBR), acrylonitrile-butadiene rubber (NBR) and carboxylated acrylonitrile-butadiene rubber (XNBR), together with the popular, commercially available Epidian 6 epoxy resin, subjected to the functionalization. An improvement in the adhesion of rubbers to silver wires was observed when using the modified resin. In some cases, an improvement in the mechanical properties of the rubber was observed, especially when the resin was used for crosslinking together with dicumyl peroxide (DCP). Crosslinking synergy between dicumyl peroxide and the modified resin could be observed especially in the case of PO applied for peroxide curing of SBR and NBR.
Databáze: MEDLINE