Emergence and Future of Exsolved Materials.

Autor: Kousi K; School of Engineering, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK., Tang C; School of Engineering, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK., Metcalfe IS; School of Engineering, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK., Neagu D; Department of Process and Chemical Engineering, University of Strathclyde, Glasgow, G1 1XL, UK.
Jazyk: angličtina
Zdroj: Small (Weinheim an der Bergstrasse, Germany) [Small] 2021 May; Vol. 17 (21), pp. e2006479. Date of Electronic Publication: 2021 Mar 31.
DOI: 10.1002/smll.202006479
Abstrakt: Supported nanoparticle systems have received increased attention over the last decades because of their potential for high activity levels when applied to chemical conversions, although, because of their nanoscale nature, they tend to exhibit problems with long-term durability. Over the last decade, the discovery of the so-called exsolution concept has addressed many of these challenges and opened many other opportunities to material design by providing a relatively simple, single-step, synthetic pathway to produce supported nanoparticles that combine high stability against agglomeration and poisoning with high activity across multiple areas of application. Here, the trends that define the development of the exsolution concept are reviewed in terms of design, functionality, tunability, and applicability. To support this, the number of studies dedicated to both fundamental and application-related studies, as well as the types of metallic nanoparticles and host or support lattices employed, are examined. Exciting future directions of research are also highlighted.
(© 2021 The Authors. Small published by Wiley-VCH GmbH.)
Databáze: MEDLINE
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