Sphagnum Inspired g-C 3 N 4 Nano/Microspheres with Smaller Bandgap in Heterojunction Membranes for Sunlight-Driven Water Purification.
Autor: | Ji L; Polymer Materials & Engineering Department, School of Materials Science & Engineering, Chang'an University, Xian, 710064, China., Yan L; Polymer Materials & Engineering Department, School of Materials Science & Engineering, Chang'an University, Xian, 710064, China., Chao M; Polymer Materials & Engineering Department, School of Materials Science & Engineering, Chang'an University, Xian, 710064, China., Li M; Polymer Materials & Engineering Department, School of Materials Science & Engineering, Chang'an University, Xian, 710064, China., Gu J; Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Science, Ningbo, 315201, China.; School of Chemical Sciences, University of Chinese Academy of Science, Beijing, 100049, China., Lei M; Polymer Materials & Engineering Department, School of Materials Science & Engineering, Chang'an University, Xian, 710064, China., Zhang Y; Polymer Materials & Engineering Department, School of Materials Science & Engineering, Chang'an University, Xian, 710064, China., Wang X; Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, China., Xia J; Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Science, Ningbo, 315201, China., Chen T; Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Science, Ningbo, 315201, China., Nie Y; Fujian Province University Key Laboratory of Modern Analytical Science and Separation Technology, College of Chemistry, Chemical Engineering and Environment, Minnan Normal University, Zhangzhou, 363000, China., Chen T; Polymer Materials & Engineering Department, School of Materials Science & Engineering, Chang'an University, Xian, 710064, China.; Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Material Technology and Engineering, Chinese Academy of Science, Ningbo, 315201, China.; School of Chemical Sciences, University of Chinese Academy of Science, Beijing, 100049, China. |
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Jazyk: | angličtina |
Zdroj: | Small (Weinheim an der Bergstrasse, Germany) [Small] 2021 Mar; Vol. 17 (12), pp. e2007122. Date of Electronic Publication: 2021 Feb 15. |
DOI: | 10.1002/smll.202007122 |
Abstrakt: | Membrane separation is recognized as one of the most effective strategies to treat the complicated wastewater system for economic development. However, serious membrane fouling has restricted its further application. Inspired by sphagnum, a 0D/2D heterojunction composite membrane is engineered by depositing graphitic carbon nitride nano/microspheres (CNMS) with plentiful wrinkles onto the polyacrylic acid functionalized carbon nanotubes (CNTs-PAA) membrane through hydrogen bond force. Through coupling unique structure and chemistry properties, the CNTs-PAA/CNMS heterojunction membrane presents superhydrophilicity and underwater superoleophobicity. Furthermore, thanks to the J-type aggregates during the solvothermal process, it is provided with a smaller bandgap (1.77 eV) than the traditional graphitic carbon nitride (g-C (© 2021 Wiley-VCH GmbH.) |
Databáze: | MEDLINE |
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