Transient Catenation in a Zirconium-Based Metal-Organic Framework and Its Effect on Mechanical Stability and Sorption Properties.

Autor:	Robison L; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States.; International Institute of Nanotechnology, Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States., Gong X; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States.; International Institute of Nanotechnology, Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States., Evans AM; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States., Son FA; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States., Wang X; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States., Redfern LR; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States., Wasson MC; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States., Syed ZH; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States.; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., Chen Z; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States., Idrees KB; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States., Islamoglu T; International Institute of Nanotechnology, Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States., Delferro M; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., Dichtel WR; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States., Coudert FX; Chimie ParisTech, PSL University, CNRS, Institut de Recherche de Chimie Paris, 75005 Paris, France., Gianneschi NC; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States.; International Institute of Nanotechnology, Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States.; Department of Biomedical Engineering, Department of Materials Science & Engineering, Department of Pharmacology, Simpson-Querrey Institute, Chemistry of Life Processes Institute, Lurie Cancer Center, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States., Farha OK; Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States.; International Institute of Nanotechnology, Department of Chemistry, Northwestern University, Evanston, Illinois 60208, United States.; Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, United States.
Jazyk:	angličtina
Zdroj:	Journal of the American Chemical Society [J Am Chem Soc] 2021 Jan 27; Vol. 143 (3), pp. 1503-1512. Date of Electronic Publication: 2021 Jan 12.
DOI:	10.1021/jacs.0c11266
Abstrakt:	Interpenetration of two or more sublattices is common among many metal-organic frameworks (MOFs). Herein, we study the evolution of one zirconium cluster-based, 3,8-connected MOF from its non-interpenetrated (NU-1200) to interpenetrated (STA-26) isomer. We observe this transient catenation process indirectly using ensemble methods, such as nitrogen porosimetry and X-ray diffraction, and directly, using high-resolution transmission electron microscopy. The approach detailed here will serve as a template for other researchers to monitor the interpenetration of their MOF samples at the bulk and single-particle limits. We investigate the mechanical stability of both lattices experimentally by pressurized in situ X-ray diffraction and nanoindentation as well as computationally with density functional theory calculations. Both lines of study reveal that STA-26 is considerably more mechanically stable than NU-1200. We conclude this study by demonstrating the potential of these MOFs and their mixed phases for the capture of gaseous n -hexane, used as a structural mimic for the chemical warfare agent sulfur mustard gas.
Databáze:	MEDLINE
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