Autor: |
Mamonova DV; Institute of Chemistry, Saint-Petersburg State University, 26 Universitetskii Prospect, Saint-Petersburg 198504, Russia., Vasileva AA; Institute of Chemistry, Saint-Petersburg State University, 26 Universitetskii Prospect, Saint-Petersburg 198504, Russia., Petrov YV; Department of Physics, Saint-Petersburg State University, Ulyanovskaya 3, Saint-Petersburg 198504, Russia., Danilov DV; Interdisciplinary Resource Center for Nanotechnology, Research Park, Saint-Petersburg State University, Ulyanovskaya 1, Saint-Petersburg 198504, Russia., Kolesnikov IE; Centre for Optical and Laser Materials Research, Research Park, Saint-Petersburg State University, Ulyanovskaya 5, Saint-Petersburg 198504, Russia., Kalinichev AA; Centre for Optical and Laser Materials Research, Research Park, Saint-Petersburg State University, Ulyanovskaya 5, Saint-Petersburg 198504, Russia., Bachmann J; Institute of Chemistry, Saint-Petersburg State University, 26 Universitetskii Prospect, Saint-Petersburg 198504, Russia.; Department of Chemistry and Pharmacy, Friedrich-Alexander University of Erlangen-Nürnberg, IZNF, Cauerst. 3, 91058 Erlangen, Germany., Manshina AA; Institute of Chemistry, Saint-Petersburg State University, 26 Universitetskii Prospect, Saint-Petersburg 198504, Russia. |
Abstrakt: |
Surfaces functionalized with metal nanoparticles (NPs) are of great interest due to their wide potential applications in sensing, biomedicine, nanophotonics, etc. However, the precisely controllable decoration with plasmonic nanoparticles requires sophisticated techniques that are often multistep and complex. Here, we present a laser-induced deposition (LID) approach allowing for single-step surface decoration with NPs of controllable composition, morphology, and spatial distribution. The formation of Ag, Pt, and mixed Ag-Pt nanoparticles on a substrate surface was successfully demonstrated as a result of the LID process from commercially available precursors. The deposited nanoparticles were characterized with SEM, TEM, EDX, X-ray diffraction, and UV-VIS absorption spectroscopy, which confirmed the formation of crystalline nanoparticles of Pt (3-5 nm) and Ag (ca. 100 nm) with plasmonic properties. The advantageous features of the LID process allow us to demonstrate the spatially selective deposition of plasmonic NPs in a laser interference pattern, and thereby, the formation of periodic arrays of Ag NPs forming diffraction grating. |